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 O3, CO, NO2, and CxHyO3NO2, & PM collect close to the ground in the air we breathe.
 Step by Step... Description of the stages of the chemical reactions that create smog.

Did You Know... Catalytic converters reduce the levels of nitrogen oxides and unburned hydrocarbons. The hydrocarbons and carbon monoxide are oxidized to carbon dioxide and water and the nitrogen oxides are reduced to nitrogen.
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he
familiar smog hanging over our cities today is created mainly by the photochemical
action of sunlight on pollutants in the exhaust from cars and trucks as
well as emissions from industry, businesses, and household products. These
pollutants, nitrogen oxide (NOx), carbon monoxide (CO), and unburned hydrocarbons
or volatile organic compounds (VOCs) are leftover from the incomplete combustion
(burning) of gasoline and other fossil fuels. There are also particulates
including smoke and lead and other gases.
Source
A series of chemical reactions are set into motion that create photochemical
smog:
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